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Passive daytime radiative cooling (PDRC) is a promising energy-saving cooling method to cool objects without energy consumption. Although numerous PDRC materials and structures have been proposed to achieve sub-ambient temperatures, the technique faces unprecedented challenges brought on by complicated and expensive fabrication. Herein, inspired by traditional Chinese oil-paper umbrellas, we develop a self-cleaning and self-cooling oil-foam composite (OFC) made of recycled polystyrene foam and tung oil to simultaneously achieve efficient passive radiative cooling and enhanced thermal dissipation of objects. The OFCs show high solar reflectance (0.90) and high mid-infrared thermal emittance (0.89) during the atmospheric transparent window, contributing to a sub-ambient temperature drop of ∼5.4 °C and cooling power of 86 W m −2 under direct solar irradiance. Additionally, the worldwide market of recycled packaging plastics can provide low-cost raw materials, further eliminating the release of plastics into the environment. The OFC offers an energy-efficient, cost-effective and environmentally friendly candidate for building cooling applications and provides a value-added path for plastic recycling. 

Configured with a rapid evaporation rate and a high photothermal conversion efficiency, solar-driven interfacial evaporation displays considerable promise for seawater desalination. Inspired by the versatility and deployability of origami-based structures, we demonstrate a portable waterbomb origami pattern-based tower-like structure, named an “origami tower”, as a convertible photothermal evaporator floating on water for efficient solar-driven interfacial desalination. The origami tower has predictable deformability, featuring reversible radial expansion and contraction radially accompanied by small changes in the axial direction. The reversible adjustability of the origami tower offers convenience for transportation and storage, while the quick expansion into its tower shape provides rapid deployment capabilities. Benefiting from an enlarged evaporation surface, excellent light trapping ability, and heat localization, the origami-tower photothermal evaporator yields an evaporation rate of 2.67 kg m −2 h −1 under one sun illumination. This reversible 3D origami-based photothermal evaporator opens a new avenue for building a portable and efficient solar thermal desalination system. 

A near-field multistage radiative thermal rectifier is proposed based on two different phase-change materials, which can achieve multistage thermal rectification with different rectification ratios. The phase-change materials vanadium dioxide (VO₂) and Ge₂Sb₂Te₅(GST), with different metal-insulator transition temperatures, are utilized within the active terminal of thermal rectifier. Four types of active terminal structures, including multi-film and composite nanograting structures, are introduced to explore to multistage thermal rectification. Our calculations find that the active terminal composed of a one-dimensional VO₂grating atop a GST thin film is the most suitable for multistage thermal rectification due to its realization of well-distributed and flexible thermal rectification. Furthermore, it is found that the passive terminal temperature of thermal rectifier can significantly affect the multistage radiative thermal rectification by modifying the rectification ratio and adjusting the stage number of multistage thermal rectification. This work sheds light on the role of different phase-change materials within the design of promising radiative thermal rectifiers boasting multistage thermal rectification.

 

Solar‐driven interfacial water evaporation powered by solar energy has gained significant interest as a sustainable and cost‐efficient desalination technology, owing to its zero reliance on fossil fuels. It aligns the relationship between freshwater demand and environmental‐friendly water yields and provides us with a feasible and effective way to mitigate the global water crisis. Biomass‐derived photothermal evaporators stemming from sustainable and renewable resources and performing high freshwater output have piqued researchers’ interest in achieving water evaporation effectively, economically, and greenly. In this review work, biomass‐based photothermal evaporators coming from hydrogels, carbides, and fibers are summarized and their optical design, wettability, thermal management, and salt‐rejection ability are analyzed, presenting an overview of the current status of biomass‐based materials in the solar‐driven water purification system.

 

Water evaporation systems with solar energy as the primary driving energy have received extensive attention in recent years. This work studies the preparation method and performance of hydrogel evaporators using chitosan and polyvinyl alcohol (PVA) as a framework and carbon nanoparticles (CNPs) as the photothermal material. The evaporation rate of CPC (chitosan/PVA and CNPs) hydrogel obtained reaches 2.28 kg m⁻² h⁻¹. Simultaneously, a three-dimensional structure is designed based on the two-dimensional double-layer evaporation system in this study. An evaporator with a tiny-pool structure and a hydrogel with a dome-arrayed structure is designed. These two structures achieve highly efficient evaporation rates of 2.28 kg m⁻² h⁻¹and 3.80 kg m⁻² h⁻¹, respectively. These optimized designs improve the evaporation rate of the overall system by ~ 66.7%. The developed evaporation devices provide a promising pathway for developing the double-layer evaporators, which promote the new development of water purification with a solar-driven evaporation system.

 

This study introduces a movable piston-like structure that provides a simple and cost-effective avenue for dynamically tuning thermal radiation. This structure leverages two materials with dissimilar optical responses—graphite and aluminum—to modulate from a state of high reflectance to a state of high absorptance. A cavity is created in the graphite to house an aluminum cylinder, which is displaced to actuate the device. In its raised state, the large aluminum surface area promotes a highly reflective response, while in its lowered state, the expanded graphite surface area and blackbody cavity-like interactions significantly enhance absorptance. By optimizing the area ratio, reflectance tunability of over 30% is achieved for nearly the entire ultraviolet, visible, and near-infrared wavelength regions. Furthermore, a theoretical analysis postulates wavelength-dependent effectivenesses as high as 0.70 for this method, indicating that tunabilities approaching 70% can be achieved by exploiting near-ideal absorbers and reflectors. The analog nature of this control method allows for an infinitely variable optical response between the upper and lower bounds of the device. These valuable characteristics would enable this material structure to serve practical applications, such as reducing cost and energy requirements for environmental temperature management operations. 

Water scarcity and waste mismanagement are global crises that threaten the health of populations worldwide and a sustainable future. In order to help mitigate both these issues, a solar desalination device composed entirely of fallen leaves and guar – both natural materials – has been developed and demonstrated herein. This sustainable desalinator realizes an evaporation rate of 2.53 kg m −2 h −1 under 1 sun irradiance, and achieves consistent performance over an extended exposure period. Furthermore, it functions efficiently under a variety of solar intensities and in high salinity environments, and can produce water at salinities well within the acceptable levels for human consumption. Such strong performance in a large variety of environmental conditions is made possible by its excellent solar absorption, superb and rapid water absorption, low thermal conductivity, and considerable salt rejection abilities. Composed primarily of biowaste material and boasting a simple fabrication process, this leaf-guar desalinator provides a low-cost and sustainable avenue for alleviating water scarcity and supporting a green path forward.